Parameters
measured in colorimetry
The effectiveness of the disinfectants
used depends on your system’s overall water chemistry, and not
just on the disinfectants’ concentrations alone. The following
section provides a brief overview on the measurement of each parameter:
BROMINE
Bromine is often used as a disinfectant in indoor or covered water systems.
Due to lower volatility, bromine is more stable in water than chlorine.
Compared to chlorine, the main advantages of bromine are reduced odour,
and skin and eye irritation. In addition, bromine remains effective
at high temperatures and its disinfecting efficiency is not affected
by pH fluctuations. The disadvantages are that bromine is more expensive
than chlorine and it cannot be stabilised for outdoor use.
Eutech’s C104 colorimeter measures bromine over the
range of 0ppm to 13.5ppm.
CHLORINE
Chlorine and chlorine-release compounds are frequently used as disinfectants
in swimming pools, drinking water and other water treatment systems.
Routine chlorination kills harmful micro-organisms. The disinfection
efficiency is a direct function of the level of free chlorine in a system.
Total chlorine is the sum of combined and free chlorine.
In applications where there is human contact with the water e.g. in
swimming pools and spas, it is essential that the right amount of chlorine
is present. Insufficient chlorine will decrease the disinfectant efficiency;
while excess chlorine will cause skin and eye irritation and become
a health hazard.
Eutech’s C401, C301 and C201 colorimeters measure
free and total chlorine over the range of 0mg/l to 6mg/l.
CHLORINE
DIOXIDE
The use of chlorine dioxide as a disinfectant is seeing growth in many
industrial applications. Unlike chlorine, chlorine dioxide remains a
true gas dissolved in solution. The lack of any significant reaction
of chlorine dioxide with water is partly responsible for its retaining
its disinfecting effectiveness over a wide pH range. This property makes
it a logical choice for cooling systems operated in the alkaline pH
range, or cooling systems with poor pH control. Other applications for
chlorine dioxide include the food processing industry; the pulp and
paper industries; and the potable water and waste treatment industries.
Eutech’s C103 colorimeter measures chlorine dioxide
over the range of 0ppm to 11.4ppm.
OZONE
Ozone is one of the strongest and most rapid oxidisers and disinfectants
available. Ozone does not require any stabiliser. It does not corrode
nor cause scaling. In addition, ozone has no smell, does not cause skin
nor eye irritation and does not pose a health hazard. Although more
expensive than traditional disinfectants like chlorine and bromine,
because it does not cause corrosion nor scaling, the long-term maintenance
cost of a water system which uses ozone as a disinfectant may be reduced
compared to using chlorine. Ozone is gaining popularity in top spas
and certain swimming pools.
Eutech’s C105 colorimeter measures ozone over the
range of 1.4ppm to 4.1ppm.
CYANURIC
ACID
In applications where chlorine is used for disinfection, cyanuric acid
is often present as a chlorine stabiliser. Low levels of cyanuric acid
are beneficial as they prevent wastage of free chlorine by the sun’s
UV rays. High levels of cyanuric acid cause the chlorine to take a longer
time to kill the micro-organisms. It is important to test your water
sample to determine how much cyanuric acid should be added to maximise
chlorine efficiency.
Eutech’s C401 and C102 colorimeters measure cyanuric
acid over the range of 5ppm to 90 ppm.
pH
The pH value affects the amount of free chlorine that is formed, and
therefore determines the effectiveness of chlorine as a disinfectant.
As pH increases, the disinfecting power of chlorine decreases. High
pH causes scaling of water surfaces, pipework and fittings; this may
result in cloudy water. Low pH can corrode metals in pipework and fittings;
this may cause metal oxides to stain water surfaces.
Eutech’s C401, C301 and C101 colorimeters measure
pH over the range of 5.9 – 8.2.
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